Вписал в /home/vadim/.config/autostart/compiz.desktop вот это:
[Desktop Entry]
Type=Application
Encoding=UTF-8
Name=Compiz
Exec=/usr/bin/compiz ccp #Make sure ccp is included so that Compiz loads your previous settings.
NoDisplay=true
# name of loadable control center module
X-MATE-WMSettingsModule=compiz
# autostart phase
##-> the folloing line cause gnome-session warning and slow startup, so try not to enable this
# X-MATE-Autostart-Phase=WindowManager
X-MATE-Provides=windowmanager
# name we put on the WM spec check window
X-MATE-WMName=Compiz
# back compat only
X-MATEWMSettingsLibrary=compiz